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Sub-micrometric LiCr0.2Ni0.4Mn1.4O4 spinel as 5 V-cathode material exhibiting huge rate capability at 25 and 55 °C

Identifieur interne : 000408 ( Main/Exploration ); précédent : 000407; suivant : 000409

Sub-micrometric LiCr0.2Ni0.4Mn1.4O4 spinel as 5 V-cathode material exhibiting huge rate capability at 25 and 55 °C

Auteurs : Mohamed Aklalouch [Espagne, Maroc] ; José Manuel Amarilla [Espagne] ; Rosa M. Rojas [Espagne] ; Ismael Saadoune [Maroc] ; José Maria Rojo [Espagne]

Source :

RBID : Pascal:10-0307662

Descripteurs français

English descriptors

Abstract

Single phase LiCr0.2Ni0.4Mn1.4O4 spinel has been synthesized by a simple sucrose assisted combustion method that yields highly crystalline homogeneous sub-micrometric samples (650 nm). The LiCr0.2-Ni0.4Mn1.4O4, with capacity retention of 92% at 60 C discharge rate, shows the highest rate capability among LiNi0.5Mn1.5O4-type cathodes. It delivers very high-power (34.8 kW kg-1 at 60 C). Studies developed at 55 °C demonstrate that LiCr0.2Ni0.4Mn1.4O4 retains huge rate capability and large cycleability at high temperature.


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Le document en format XML

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<title xml:lang="en" level="a">Sub-micrometric LiCr
<sub>0.2</sub>
Ni
<sub>0.4</sub>
Mn
<sub>1.4</sub>
O
<sub>4</sub>
spinel as 5 V-cathode material exhibiting huge rate capability at 25 and 55 °C</title>
<author>
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<analytic>
<title xml:lang="en" level="a">Sub-micrometric LiCr
<sub>0.2</sub>
Ni
<sub>0.4</sub>
Mn
<sub>1.4</sub>
O
<sub>4</sub>
spinel as 5 V-cathode material exhibiting huge rate capability at 25 and 55 °C</title>
<author>
<name sortKey="Aklalouch, Mohamed" sort="Aklalouch, Mohamed" uniqKey="Aklalouch M" first="Mohamed" last="Aklalouch">Mohamed Aklalouch</name>
<affiliation wicri:level="2">
<inist:fA14 i1="01">
<s1>Instituto de Ciencia de Materiales de Madrid (CSIC), c/Sor Juana Inés de la Cruz, 3 Cantoblanco</s1>
<s2>28049 Madrid</s2>
<s3>ESP</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName>
<region nuts="2" type="communauté">Communauté de Madrid</region>
</placeName>
</affiliation>
<affiliation wicri:level="3">
<inist:fA14 i1="02">
<s1>ECME, Faculté des Sciences et Techniques Marrakech, (UCAM) Av. A. ElKhattabi, B.P. 549</s1>
<s2>Marrakech</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName>
<settlement type="city">Marrakech</settlement>
<region nuts="2">Marrakech-Tensift-Al Haouz</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Amarilla, Jose Manuel" sort="Amarilla, Jose Manuel" uniqKey="Amarilla J" first="José Manuel" last="Amarilla">José Manuel Amarilla</name>
<affiliation wicri:level="2">
<inist:fA14 i1="01">
<s1>Instituto de Ciencia de Materiales de Madrid (CSIC), c/Sor Juana Inés de la Cruz, 3 Cantoblanco</s1>
<s2>28049 Madrid</s2>
<s3>ESP</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName>
<region nuts="2" type="communauté">Communauté de Madrid</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Rojas, Rosa M" sort="Rojas, Rosa M" uniqKey="Rojas R" first="Rosa M." last="Rojas">Rosa M. Rojas</name>
<affiliation wicri:level="2">
<inist:fA14 i1="01">
<s1>Instituto de Ciencia de Materiales de Madrid (CSIC), c/Sor Juana Inés de la Cruz, 3 Cantoblanco</s1>
<s2>28049 Madrid</s2>
<s3>ESP</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName>
<region nuts="2" type="communauté">Communauté de Madrid</region>
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<author>
<name sortKey="Saadoune, Ismael" sort="Saadoune, Ismael" uniqKey="Saadoune I" first="Ismael" last="Saadoune">Ismael Saadoune</name>
<affiliation wicri:level="3">
<inist:fA14 i1="02">
<s1>ECME, Faculté des Sciences et Techniques Marrakech, (UCAM) Av. A. ElKhattabi, B.P. 549</s1>
<s2>Marrakech</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName>
<settlement type="city">Marrakech</settlement>
<region nuts="2">Marrakech-Tensift-Al Haouz</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Rojo, Jose Maria" sort="Rojo, Jose Maria" uniqKey="Rojo J" first="José Maria" last="Rojo">José Maria Rojo</name>
<affiliation wicri:level="2">
<inist:fA14 i1="01">
<s1>Instituto de Ciencia de Materiales de Madrid (CSIC), c/Sor Juana Inés de la Cruz, 3 Cantoblanco</s1>
<s2>28049 Madrid</s2>
<s3>ESP</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName>
<region nuts="2" type="communauté">Communauté de Madrid</region>
</placeName>
</affiliation>
</author>
</analytic>
<series>
<title level="j" type="main">Electrochemistry communications</title>
<title level="j" type="abbreviated">Electrochem. commun.</title>
<idno type="ISSN">1388-2481</idno>
<imprint>
<date when="2010">2010</date>
</imprint>
</series>
</biblStruct>
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<seriesStmt>
<title level="j" type="main">Electrochemistry communications</title>
<title level="j" type="abbreviated">Electrochem. commun.</title>
<idno type="ISSN">1388-2481</idno>
</seriesStmt>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Cathode</term>
<term>Chromium Oxides</term>
<term>Comparative study</term>
<term>Cycling</term>
<term>Discharge</term>
<term>Discharge charge cycle</term>
<term>Electrical characteristic</term>
<term>Electrode material</term>
<term>Lithium Oxides</term>
<term>Lithium battery</term>
<term>Manganese Oxides</term>
<term>Morphology</term>
<term>Multi-element compound</term>
<term>Nickel Oxides</term>
<term>Particle size</term>
<term>Particle size distribution</term>
<term>Preparation</term>
<term>Quaternary compound</term>
<term>Scanning electron microscopy</term>
<term>Secondary cell</term>
<term>Specific capacity</term>
<term>Spinels</term>
<term>Surface structure</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Spinelles</term>
<term>Cathode</term>
<term>Matériau électrode</term>
<term>Cycle charge décharge</term>
<term>Batterie lithium</term>
<term>Composé quaternaire</term>
<term>Lithium Oxyde</term>
<term>Nickel Oxyde</term>
<term>Manganèse Oxyde</term>
<term>Chrome Oxyde</term>
<term>Composé n éléments</term>
<term>Etude comparative</term>
<term>Diffraction RX</term>
<term>Microscopie électronique balayage</term>
<term>Distribution dimension particule</term>
<term>Cyclage</term>
<term>Capacité spécifique</term>
<term>Préparation</term>
<term>Décharge</term>
<term>Caractéristique électrique</term>
<term>Accumulateur électrochimique</term>
<term>Structure surface</term>
<term>Morphologie</term>
<term>Dimension particule</term>
</keywords>
</textClass>
</profileDesc>
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<front>
<div type="abstract" xml:lang="en">Single phase LiCr
<sub>0.2</sub>
Ni
<sub>0.4</sub>
Mn
<sub>1.4</sub>
O
<sub>4</sub>
spinel has been synthesized by a simple sucrose assisted combustion method that yields highly crystalline homogeneous sub-micrometric samples (650 nm). The LiCr
<sub>0.2</sub>
-Ni
<sub>0.4</sub>
Mn
<sub>1.4</sub>
O
<sub>4</sub>
, with capacity retention of 92% at 60 C discharge rate, shows the highest rate capability among LiNi
<sub>0.5</sub>
Mn
<sub>1.5</sub>
O
<sub>4</sub>
-type cathodes. It delivers very high-power (34.8 kW kg
<sup>-1</sup>
at 60 C). Studies developed at 55 °C demonstrate that LiCr
<sub>0.2</sub>
Ni
<sub>0.4</sub>
Mn
<sub>1.4</sub>
O
<sub>4</sub>
retains huge rate capability and large cycleability at high temperature.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>Espagne</li>
<li>Maroc</li>
</country>
<region>
<li>Communauté de Madrid</li>
<li>Marrakech-Tensift-Al Haouz</li>
</region>
<settlement>
<li>Marrakech</li>
</settlement>
</list>
<tree>
<country name="Espagne">
<region name="Communauté de Madrid">
<name sortKey="Aklalouch, Mohamed" sort="Aklalouch, Mohamed" uniqKey="Aklalouch M" first="Mohamed" last="Aklalouch">Mohamed Aklalouch</name>
</region>
<name sortKey="Amarilla, Jose Manuel" sort="Amarilla, Jose Manuel" uniqKey="Amarilla J" first="José Manuel" last="Amarilla">José Manuel Amarilla</name>
<name sortKey="Rojas, Rosa M" sort="Rojas, Rosa M" uniqKey="Rojas R" first="Rosa M." last="Rojas">Rosa M. Rojas</name>
<name sortKey="Rojo, Jose Maria" sort="Rojo, Jose Maria" uniqKey="Rojo J" first="José Maria" last="Rojo">José Maria Rojo</name>
</country>
<country name="Maroc">
<region name="Marrakech-Tensift-Al Haouz">
<name sortKey="Aklalouch, Mohamed" sort="Aklalouch, Mohamed" uniqKey="Aklalouch M" first="Mohamed" last="Aklalouch">Mohamed Aklalouch</name>
</region>
<name sortKey="Saadoune, Ismael" sort="Saadoune, Ismael" uniqKey="Saadoune I" first="Ismael" last="Saadoune">Ismael Saadoune</name>
</country>
</tree>
</affiliations>
</record>

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